9. Electronic effects of the sulphonium group

  1. C. J. M. Stirling
  1. John Shorter

Published Online: 16 JAN 2010

DOI: 10.1002/9780470771648.ch9

The Sulphonium Group: Volume 1 (1981)

The Sulphonium Group: Volume 1 (1981)

How to Cite

Shorter, J. (1981) Electronic effects of the sulphonium group, in The Sulphonium Group: Volume 1 (1981) (ed C. J. M. Stirling), John Wiley & Sons, Ltd., Chichester, UK. doi: 10.1002/9780470771648.ch9

Editor Information

  1. School of Physical and Molecular Sciences, University College of North Wales, Bangor

Author Information

  1. Department of Chemistry, The University, Hull HU6 7RX, England

Publication History

  1. Published Online: 16 JAN 2010
  2. Published Print: 8 APR 1981

ISBN Information

Print ISBN: 9780471277699

Online ISBN: 9780470771648

SEARCH

Keywords:

  • sulphur atom;
  • molecular orbitals;
  • electronic structure;
  • dimethyl sulphide;
  • methyl cation

Summary

This chapter contains sections titled:

  • Introduction

  • The Hammett Equation20

  • Sigma Values in Aromatic Systems

  • Electronic Effects in Electrophilic Substitution

  • Electronic Effects in Nucleophilic Substiution

  • Stabilization of Carbanionic Centres by the Sulphonium Group

  • Electronic Effects in Aliphatic Systems

  • The Ortho-Effect of the Sulphonium Group

  • The Irrelevance of D-Orbital Conjugation(?)

  • References and Notes