18. Special properties of di- and polyamines

  1. Saul Patai
  1. Roger W. Alder1 and
  2. Richard B. Sessions2

Published Online: 16 JAN 2010

DOI: 10.1002/9780470771679.ch3

Amino, Nitrosco and Nitro Compounds and Their Derivatives: Volume 2 (1982)

Amino, Nitrosco and Nitro Compounds and Their Derivatives: Volume 2 (1982)

How to Cite

Alder, R. W. and Sessions, R. B. (1982) Special properties of di- and polyamines, in Amino, Nitrosco and Nitro Compounds and Their Derivatives: Volume 2 (1982) (ed S. Patai), John Wiley & Sons, Ltd., Chichester, UK. doi: 10.1002/9780470771679.ch3

Editor Information

  1. The Hebrew University, Jerusalem

Author Information

  1. 1

    School of Chemistry, University of Bristol, Bristol BS8 1TS, England

  2. 2

    Institut Le Bel, Université Louis Pasteur, 1 Rue Blaise Pascal, 67008 Strasbourg, France

Publication History

  1. Published Online: 16 JAN 2010
  2. Published Print: 29 APR 1982

ISBN Information

Print ISBN: 9780471278726

Online ISBN: 9780470771679

SEARCH

Keywords:

  • metal ion;
  • molecular constraints;
  • photoelectron spectra;
  • structural change;
  • proton transfer

Summary

This chapter contains sections titled:

  • Introdcution

  • A Simple Theoretical Picture of Interactions Amongst Lone Pairs

  • Structural Consequences of the Avoidance of Lone-Pair Repulsion

  • Photoelectron Spectra of Diamines

  • Electrochemistry of di and polyamines

  • Diamine Radical Cations and Dications

  • Intramolecular Hydrogen Bonding in Diamines and Their Monoprotonated Ions

  • Gas-Phase Proton Affinities of Diamines

  • Basicity of Diamines in Aqueous Solution

  • Proton-Transfer Rates Involving Diamines

  • Metal Complexation by Di- and Poly-Amines

  • References