10. Transition metal-stabilized carbocations in organic synthesis

  1. Frank R. Hartley
  1. A. J. Pearson

Published Online: 21 JAN 2010

DOI: 10.1002/9780470771778.ch10

The Metal - Carbon Bond: Volume 4 (1987)

The Metal - Carbon Bond: Volume 4 (1987)

How to Cite

Pearson, A. J. (1987) Transition metal-stabilized carbocations in organic synthesis, in The Metal - Carbon Bond: Volume 4 (1987) (ed F. R. Hartley), John Wiley & Sons, Inc., Chichester, UK. doi: 10.1002/9780470771778.ch10

Editor Information

  1. The Royal Military College of Science, Shrivenham, England

Author Information

  1. Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, USA

Publication History

  1. Published Online: 21 JAN 2010
  2. Published Print: 8 APR 1987

ISBN Information

Print ISBN: 9780471908883

Online ISBN: 9780470771778

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Keywords:

  • organometallic;
  • synthons;
  • reaction equivalents;
  • michael addition;
  • robinson annulation

Summary

This chapter contains sections titled:

  • Introduction

  • Role of The Transition Metal In Cationic Complexes

  • η2-Alkene Complexes

  • η3-Allyl Complexes

  • Cationic η4-Diene Complexes

  • Cationic η5-Dienyl Complexes

  • Propargyl Cations Stabilized by Cobalt

  • Arene-Metal Complexes

  • References