6. Preparation and use of organosilicon compounds in organic synthesis

  1. Frank R. Hartley
  1. E. W. Colvin

Published Online: 21 JAN 2010

DOI: 10.1002/9780470771778.ch6

The Metal - Carbon Bond: Volume 4 (1987)

The Metal - Carbon Bond: Volume 4 (1987)

How to Cite

Colvin, E. W. (1987) Preparation and use of organosilicon compounds in organic synthesis, in The Metal - Carbon Bond: Volume 4 (1987) (ed F. R. Hartley), John Wiley & Sons, Inc., Chichester, UK. doi: 10.1002/9780470771778.ch6

Editor Information

  1. The Royal Military College of Science, Shrivenham, England

Author Information

  1. Chemistry Department, University of Glasgow, Glasgow G12 8QQ, UK

Publication History

  1. Published Online: 21 JAN 2010
  2. Published Print: 8 APR 1987

ISBN Information

Print ISBN: 9780471908883

Online ISBN: 9780470771778

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Keywords:

  • ferryman;
  • anhydrous;
  • carbanionoids;
  • Pummerer rearrangement;
  • electrophiles

Summary

This chapter contains sections titled:

  • Introduction

  • Physical Properties of Organosilicon Compounds

  • Rearrangement Reactions

  • Vinylsilanes

  • α, β-Epoxysilanes

  • Allylsilanes

  • Arylsilanes

  • Organosilyl Anions/Anionoids

  • β-Functional Organosilanes and Peterson Olefination

  • Alkynyl- and Allenyl-Silanes

  • Cyclopropyl- and Cyclopropylcarbinyl-Silanes

  • Alkyl Silyl Ethers

  • Silyl Enol Ethers and Ketene Acetals

  • Silyl-Based Reagents

  • Aminosilanes and Related Compounds

  • Silanes as Reducing Agents

  • Acylsilanes

  • α-Silyl Radicals

  • Conclusions

  • References