Chapter 4. Fundamental Reactions on Rutile TiO2(110) Model Photocatalysts Studied by High-Resolution Scanning Tunneling Microscopy

  1. Lionel Vayssieres
  1. Stefan Wendt,
  2. Ronnie T. Vang,
  3. Flemming Besenbacher

Published Online: 2 MAR 2010

DOI: 10.1002/9780470823996.ch4

On Solar Hydrogen & Nanotechnology

On Solar Hydrogen & Nanotechnology

How to Cite

Wendt, S., Vang, R. T. and Besenbacher, F. (2010) Fundamental Reactions on Rutile TiO2(110) Model Photocatalysts Studied by High-Resolution Scanning Tunneling Microscopy, in On Solar Hydrogen & Nanotechnology (ed L. Vayssieres), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470823996.ch4

Editor Information

  1. National Institute for Materials Science, Japan

Author Information

  1. Interdisciplinary Nanoscience Center (iNANO), Department of Physics and Astronomy, Ny Munkegade, Building 1521, Aarhus University, DK-8000 Aarhus C, Denmark

Publication History

  1. Published Online: 2 MAR 2010
  2. Published Print: 4 JAN 2010

ISBN Information

Print ISBN: 9780470823972

Online ISBN: 9780470823996

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Keywords:

  • TiO2;
  • water;
  • hydrogen;
  • oxygen;
  • gold;
  • photocatalysis;
  • CO oxidation;
  • scanning tunnelling microscopy;
  • photoelectron spectroscopy;
  • density functional theory

Summary

Scanning Tunnelling Microscopy, Photoelectron Spectroscopy and Density Functional Theory simulations are used to identify reaction pathways, active sites and the electronic defects on rutile TiO2(110). Examples from our laboratory show how fundamental work performed under ultra-high vacuum conditions helps to improve our understanding of important aspects of catalysis and photocatalysis.