9. Carbanions and Electrophilic Aliphatic Substitution

  1. A. C. Knipe
  1. M. L. Birsa

Published Online: 5 AUG 2011

DOI: 10.1002/9780470975800.ch9

Organic Reaction Mechanisms · 2007: An annual survey covering the literature dated January to December 2007

Organic Reaction Mechanisms · 2007: An annual survey covering the literature dated January to December 2007

How to Cite

Birsa, M. L. (2007) Carbanions and Electrophilic Aliphatic Substitution, in Organic Reaction Mechanisms · 2007: An annual survey covering the literature dated January to December 2007 (ed A. C. Knipe), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470975800.ch9

Editor Information

  1. Faculty of Life and Health Sciences, University of Ulster, Coleraine, Northern Ireland

Author Information

  1. Department of Chemistry, “Al. I. Cuza” University of Iasi, Bd. Carol I, 11, Iasi 700506, Romania

Publication History

  1. Published Online: 5 AUG 2011
  2. Published Print: 3 DEC 2007

ISBN Information

Print ISBN: 9780470712382

Online ISBN: 9780470975800

SEARCH

Keywords:

  • carbanions and electrophilic aliphatic substitution;
  • carbanion structure and stability;
  • pyridine regioselective deprotonation in gas phase - using chemical reactivity studies;
  • carbanion reactions - enolates and related species;
  • desymmetrization of centrosymmetric molecules - by enantioselective carbon[BOND]carbon bond formation, convergent synthetic approach;
  • nucleophilic opening of functionalized azetidinium ions by C-nucleophiles;
  • organocatalytic asymmetric reactions - new methodologies, catalyst design and synthetic applications;
  • novel class of sulfinamido alcohol ligands - synthesized from (S)-t -butanesulfinamide;
  • homoallylic alcohols bearing adjacent quaternary centres - diastereoselective synthesis, using substituted allylic zinc reagents;
  • electrophilic aliphatic substitution

Summary

This chapter contains sections titled:

  • Carbanion Structure and Stability

  • Carbanion Reactions

  • Proton-transfer Reactions

  • Miscellaneous

  • Electrophilic Aliphatic Substitution

  • References