5. Catalytic Strategies for Converting Lignocellulosic Carbohydrates to Fuels and Chemicals

  1. Charles E. Wyman3,4
  1. Jesse Q. Bond1,
  2. David Martin Alonso2 and
  3. James A. Dumesic2

Published Online: 5 APR 2013

DOI: 10.1002/9780470975831.ch5

Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals

Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals

How to Cite

Bond, J. Q., Alonso, D. M. and Dumesic, J. A. (2013) Catalytic Strategies for Converting Lignocellulosic Carbohydrates to Fuels and Chemicals, in Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals (ed C. E. Wyman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470975831.ch5

Editor Information

  1. 3

    Department of Chemical and Environmental Engineering and Center for Environmental Research and Technology, University of California, Riverside, USA

  2. 4

    BioEnergy Science Center, Oak Ridge, USA

Author Information

  1. 1

    Biomedical and Chemical Engineering, Syracuse University, Syracuse, USA

  2. 2

    Department of Chemical and Biological Engineering, University of Wisconsin, Madison, USA

Publication History

  1. Published Online: 5 APR 2013
  2. Published Print: 10 MAY 2013

Book Series:

  1. Wiley Series in Renewable Resources

Book Series Editors:

  1. Christian V. Stevens

Series Editor Information

  1. Faculty of Bioscience Engineering, Ghent University, Ghent, Belgium

ISBN Information

Print ISBN: 9780470972021

Online ISBN: 9780470975831



  • biorefining;
  • catalytic conversion;
  • lignocellulose;
  • renewable fuels;
  • renewable chemicals;
  • sustainable industry;
  • sugar processing


The goal of biomass pretreatment is to efficiently recover and process carbohydrate polymers (and their respective monomeric sugars) comprising lignocellulosic biomass. Here, the use of these carbohydrates is considered as a sustainable feedstock for industrial carbon. Carbohydrates are markedly distinct from the fossil resources predominately used in the modern production of both fuels and chemicals. The implications of these differences are outlined, particularly in terms of upgrading strategies associated with each feedstock. Chemically, sugars are extensively functionalized molecules because each carbon in the molecule is bound to an oxygen atom. Compared to petroleum-sourced alkane feedstocks, this functionality imparts a generally low energy density and high reactivity; they therefore require processing strategies that differ from current petroleum-based approaches. If they are to yield presently available consumer products, carbohydrates must undergo extensive chemical transformations enabling fuel and chemical production. To achieve the desired transformations, there are multiple options available. Although a general overview is provided, the focus of this chapter is catalytic methods to achieve selective transformations of biomass-derived intermediates. Catalysis allows tailored control of chemical selectivity in upgrading strategies, which is imperative for achieving high-yield production of intermediates from over-functionalized feedstocks (sugars). Upgrading strategies typically proceed through multiple intermediate stages. In this regard, heterogeneous catalysis is particularly attractive because it enables process intensification through condensed strategies that couple multiple transformations in single reactors with straightforward catalyst recovery. Finally, solid catalysts are characteristically robust and may be applied over a broad range of reaction conditions. As such, they can expedite biorefining strategies by simultaneously allowing selective and rapid feedstock conversion at high temperatures and feed concentrations. A variety of catalytic pathways are considered by which the functionality of carbohydrates and derived intermediates may be reduced (e.g., hydrogenolysis to improve energy density for producing fuel additives) or increased (e.g., oxidation to facilitate production of specialty chemicals). This chapter assembles a general roadmap of the multiple options available for value-added processing of carbohydrates, offering readers both a historical view of advances in the field and a look forward to ways in which catalysis will continue to shape the advance of biorefining to a commercial scale.