12. Asymmetric Polymerizations of N-Substituted Maleimides

  1. Shinichi Itsuno
  1. Kenjiro Onimura and
  2. Tsutomu Oishi

Published Online: 27 JUN 2011

DOI: 10.1002/9781118063965.ch12

Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis

Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis

How to Cite

Onimura, K. and Oishi, T. (2011) Asymmetric Polymerizations of N-Substituted Maleimides, in Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis (ed S. Itsuno), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118063965.ch12

Editor Information

  1. Toyohashi University of Technology, Toyohashi, Japan

Author Information

  1. Yamaguchi University, Yamaguchi, Japan

Publication History

  1. Published Online: 27 JUN 2011
  2. Published Print: 15 AUG 2011

ISBN Information

Print ISBN: 9780470568200

Online ISBN: 9781118063965

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Keywords:

  • asymmetric polymerizations of N-substituted maleimides - polymer chain chirality;
  • anionic polymerization mechanism of RMI - nucleophilic attack of carbanion;
  • free radical, polymerization stereochemistry control - using radical catalysis in industry

Summary

This chapter contains sections titled:

  • Introduction

  • Chirality of 1-Mono- or 1,1-Disubstituted and 1,2-Disubstituted Olefins

  • Asymmetric Polymerizations of Achiral N-Substituted Maleimides

  • Anionic Polymerization Mechanism of RMI

  • Asymmetric Polymerizations of Chiral N-Substituted Maleimides

  • Structure and Absolute Stereochemistry of Poly(RMI)

  • Asymmetric Radical Polymerizations of N-Substituted Maleimides

  • Chiral Discrimination Using Poly(RMI)

  • Conclusions

  • References