11. Recent Advances on Stereoselective Organocatalytic Reactions. Organocatalytic Synthesis of Natural Products and Drugs

  1. Michelangelo Gruttadauria and
  2. Francesco Giacalone
  1. Monika Raj and
  2. Vinod K. Singh

Published Online: 7 JUL 2011

DOI: 10.1002/9781118087992.ch11

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

How to Cite

Raj, M. and Singh, V. K. (2011) Recent Advances on Stereoselective Organocatalytic Reactions. Organocatalytic Synthesis of Natural Products and Drugs, in Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications (eds M. Gruttadauria and F. Giacalone), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118087992.ch11

Editor Information

  1. Department of Molecular and Biomolecular Sciences (STEMBIO), Section of Organic Chemistry, University of Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy

Author Information

  1. Indian Institute of Science Education and Research, Bhopal Transit Campus: ITI Campus (Gas Rahat) Building, Govindpura, Bhopal—460 023 India

Publication History

  1. Published Online: 7 JUL 2011
  2. Published Print: 1 AUG 2011

ISBN Information

Print ISBN: 9780470641361

Online ISBN: 9781118087992

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Keywords:

  • recent advances, in organocatalytic, enzymatic and metal-based mediated asymmetric synthesis - stereoselective organocatalytic reactions;
  • dienamine catalysis, mechanism of β-functionalization - in α, β-unsaturated carbonyl compounds;
  • Brønsted acids and chiral hydrogen bond donors - asymmetric catalysis, hydrogen bond to electrophile

Summary

This chapter contains sections titled:

  • Introduction

  • Enamine catalysis

  • Iminium catalysis

  • Dienamine catalysis

  • SOMO activation

  • Brønsted acid and hydrogen bond catalysis

  • Brønsted base catalysis

  • Bifunctional catalysis

  • Phase transfer catalysis

  • Conclusions and future perspective

  • References