13. Peptides for Asymmetric Catalysis

  1. Michelangelo Gruttadauria and
  2. Francesco Giacalone
  1. Matthias Freund and
  2. Svetlana B. Tsogoeva

Published Online: 7 JUL 2011

DOI: 10.1002/9781118087992.ch13

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

How to Cite

Freund, M. and Tsogoeva, S. B. (2011) Peptides for Asymmetric Catalysis, in Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications (eds M. Gruttadauria and F. Giacalone), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118087992.ch13

Editor Information

  1. Department of Molecular and Biomolecular Sciences (STEMBIO), Section of Organic Chemistry, University of Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy

Author Information

  1. Department of Chemistry and Pharmacy, Chair of Organic Chemistry I, University of Erlangen-Nuremberg, Henkestrasse 42, 91054 Erlangen, Germany

Publication History

  1. Published Online: 7 JUL 2011
  2. Published Print: 1 AUG 2011

ISBN Information

Print ISBN: 9780470641361

Online ISBN: 9781118087992

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Keywords:

  • peptides for asymmetric catalysis, short peptides and peptide-like molecules - catalysts, with enzyme-like character;
  • peptide-catalyzed asymmetric aldol reactions - L-proline amides and L-proline-based short peptides, catalysts;
  • peptide-catalyzed desymmetrization reaction - catalyzed by peptide 38

Summary

This chapter contains sections titled:

  • Introduction

  • Cyanation of aldehydes and Strecker reaction

  • Peptide-catalyzed asymmetric 1,4-conjugate addition reactions

  • Peptide-catalyzed asymmetric aldol reactions

  • Peptide-catalyzed asymmetric Morita–Baylis–Hillman reactions

  • Peptide-catalyzed Stetter reaction

  • Peptide-catalyzed regioselective acylation reactions

  • Peptide-catalyzed asymmetric α-functionalizations

  • Peptide-catalyzed desymmetrization reaction

  • Peptide-catalyzed kinetic resolutions

  • Peptide-catalyzed asymmetric protonation reactions

  • Peptide-catalyzed asymmetric transfer hydrogenation reactions

  • Summary

  • References