14. Silicate-Mediated Stereoselective Reactions Catalyzed by Chiral Lewis Bases

  1. Michelangelo Gruttadauria and
  2. Francesco Giacalone
  1. Maurizio Benaglia,
  2. Stefania Guizzetti and
  3. Sergio Rossi

Published Online: 7 JUL 2011

DOI: 10.1002/9781118087992.ch14

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

How to Cite

Benaglia, M., Guizzetti, S. and Rossi, S. (2011) Silicate-Mediated Stereoselective Reactions Catalyzed by Chiral Lewis Bases, in Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications (eds M. Gruttadauria and F. Giacalone), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118087992.ch14

Editor Information

  1. Department of Molecular and Biomolecular Sciences (STEMBIO), Section of Organic Chemistry, University of Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy

Author Information

  1. Dipartimento di Chimica Organica e Industriale, Universitàdegli Studi di Milano, via Golgi 19, 20133 Milano, Italy

Publication History

  1. Published Online: 7 JUL 2011
  2. Published Print: 1 AUG 2011

ISBN Information

Print ISBN: 9780470641361

Online ISBN: 9781118087992

SEARCH

Keywords:

  • silicate-mediated stereoselective reactions, chiral Lewis bases - organocatalytic approach, green chemistry principles;
  • stereoselective catalytic reduction - promoted by oxazoline-based chiral catalyst;
  • ring-opening reaction of epoxides - enantioselectivity and substrate structure

Summary

This chapter contains sections titled:

  • Introduction

  • Stereoselective C[BOND]H bond formation

  • Stereoselective C[BOND]C bond formation

  • Ring-opening reaction of epoxides

  • Miscellaneous

  • Outlook and perspectives

  • References