6. Catalysis with Chirally Modified Metal Surfaces: Scope and Mechanisms

  1. Michelangelo Gruttadauria and
  2. Francesco Giacalone
  1. Angelo Vargas,
  2. Cecilia Mondelli and
  3. Alfons Baiker

Published Online: 7 JUL 2011

DOI: 10.1002/9781118087992.ch6

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications

How to Cite

Vargas, A., Mondelli, C. and Baiker, A. (2011) Catalysis with Chirally Modified Metal Surfaces: Scope and Mechanisms, in Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications (eds M. Gruttadauria and F. Giacalone), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118087992.ch6

Editor Information

  1. Department of Molecular and Biomolecular Sciences (STEMBIO), Section of Organic Chemistry, University of Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy

Author Information

  1. Department of Chemical and Applied Biosciences, ETH Zurich, Switzerland, Wolfgang-Pauli-Str. 10, ETH Hönggerberg, HCI E 133, CH-8093 Zürich, Switzerland

Publication History

  1. Published Online: 7 JUL 2011
  2. Published Print: 1 AUG 2011

ISBN Information

Print ISBN: 9780470641361

Online ISBN: 9781118087992

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Keywords:

  • catalysis, chirally modified metal surfaces - enantioselective catalysis, amplification;
  • scope of catalysis, chirally modified metals, Pt, Pd, Ni, Rh, Ir metals - cinchona alkaloids;
  • chirally modified metal surfaces - ketone and C[DOUBLE BOND]C double bond asymmetric hydrogenation

Summary

This chapter contains sections titled:

  • Introduction to chirally modified metal surfaces

  • Asymmetric reactions at chirally modified metal surfaces

  • The development of a model for the Cinchona alkaloid modified platinum asymmetric hydrogenation

  • Conclusions

  • References