6. Structure and Reactivity of Copper–Oxygen Species Revealed by Competitive Oxygen-18 Isotope Effects

  1. Kenneth D. Karlin1 and
  2. Shinobu Itoh2
  1. Justine P. Roth

Published Online: 11 AUG 2011

DOI: 10.1002/9781118094365.ch6

Copper-Oxygen Chemistry

Copper-Oxygen Chemistry

How to Cite

Roth, J. P. (2011) Structure and Reactivity of Copper–Oxygen Species Revealed by Competitive Oxygen-18 Isotope Effects, in Copper-Oxygen Chemistry (eds K. D. Karlin and S. Itoh), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118094365.ch6

Editor Information

  1. 1

    Department of Chemistry, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA

  2. 2

    Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan

Author Information

  1. Department of Chemistry, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA

Publication History

  1. Published Online: 11 AUG 2011
  2. Published Print: 16 SEP 2011

ISBN Information

Print ISBN: 9780470528358

Online ISBN: 9781118094365

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Keywords:

  • structure and reactivity of copper–oxygen species - by competitive oxygen-18 isotope effects;
  • oxygen kinetic isotope effects (18O KIEs) - new approach, O2 with synthetic copper complexes and copper proteins;
  • copper enzyme mechanisms, competitive 18O isotope fractionation technique - and dioxygen-utilizing enzymes

Summary

This chapter contains sections titled:

  • Introduction

  • Instrumentation

  • Methodology

  • Oxygen equilibrium isotope effects

  • Oxygen kinetic isotope effects

  • Mechanisms of copper enzymes

  • Conclusions

  • Acknowledgments

  • References