1. Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design

  1. Paul C. J. Kamer2 and
  2. Piet W. N. M. van Leeuwen3
  1. Jason A. Gillespie2,
  2. Erik Zuidema1,
  3. Piet W. N. M. van Leeuwen3 and
  4. Paul C. J. Kamer2

Published Online: 9 MAY 2012

DOI: 10.1002/9781118299715.ch1

Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis

Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis

How to Cite

Gillespie, J. A., Zuidema, E., van Leeuwen, P. W. N. M. and Kamer, P. C. J. (2012) Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design, in Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis (eds P. C. J. Kamer and P. W. N. M. van Leeuwen), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781118299715.ch1

Editor Information

  1. 2

    EaStCHEM, School of Chemistry, University of St Andrews Purdie Building, North Haugh St Andrews, Fife KY16 9ST United Kingdom

  2. 3

    Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain

Author Information

  1. 1

    SABIC Technology & Innovation, Urmonderbaan 22, 6167 RD Geleen, The Netherlands

  2. 2

    EaStCHEM, School of Chemistry, University of St Andrews Purdie Building, North Haugh St Andrews, Fife KY16 9ST United Kingdom

  3. 3

    Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain

Publication History

  1. Published Online: 9 MAY 2012
  2. Published Print: 29 JUN 2012

ISBN Information

Print ISBN: 9780470666272

Online ISBN: 9781118299715

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Keywords:

  • phosphorus ligand in transition metal homogeneous catalysis;
  • phosphorus(III) donor ligands, in catalytic reactions;
  • transition metal complex optimisation, catalysis and ligand libraries;
  • new catalyst and choice of metal, metal reactivity adding donor ligands;
  • phosphorus ligands on transition metal, properties;
  • MESP, Tolman steric, electronic, sphere ligands on transition metal;
  • asymmetric hydrogenation, and bidentate phosphine ligand use;
  • rational catalyst design in nickel-catalysed hydrocyanation;
  • organotransition reactivity, ligand change predicting catalytic behaviour;
  • novel catalysts, right steric, electronic ligand properties

Summary

This chapter contains sections titled:

  • Introduction

  • Properties of phosphorus ligands

  • Asymmetric ligands

  • Rational ligand design in nickel-catalysed hydrocyanation

  • Conclusions

  • References