7. Selective Oxidation

  1. John Whittall6 and
  2. Peter W. Sutton7
  1. Valentin Köhler6,
  2. Bas Groenendaal6,
  3. Kevin R. Bailey6,
  4. Anass Znabet6,
  5. James Raferty6,
  6. Madeleine Helliwell6,
  7. Nicholas J. Turner6,
  8. Kristian Geitner1,
  9. Uwe T. Bornscheuer1,
  10. Gonzalo de Gonzalo3,
  11. Vicente Gotor3,
  12. Shuvendu Das4,
  13. John P. N. Rosazza4,
  14. Aashrita Rajagopalan5,
  15. Francesco G. Mutti5 and
  16. Wolfgang Kroutil5

Published Online: 13 MAY 2012

DOI: 10.1002/9781119943426.ch7

Practical Methods for Biocatalysis and Biotransformations 2

Practical Methods for Biocatalysis and Biotransformations 2

How to Cite

Köhler, V., Groenendaal, B., Bailey, K. R., Znabet, A., Raferty, J., Helliwell, M., Turner, N. J., Geitner, K., Bornscheuer, U. T., de Gonzalo, G., Gotor, V., Das, S., Rosazza, J. P. N., Rajagopalan, A., Mutti, F. G. and Kroutil, W. (2012) Selective Oxidation, in Practical Methods for Biocatalysis and Biotransformations 2 (eds J. Whittall and P. W. Sutton), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119943426.ch7

Editor Information

  1. 6

    Manchester Interdisciplinary Biocentre (MIB), The University of Manchester, 131 Princess Street, Manchester, M1 7DN, UK

  2. 7

    GlaxoSmithKline Research and Development Limited, Gunnels Wood Road, Stevenage, Hertfordshire, SG1 2NY, UK

Author Information

  1. 1

    Department of Biotechnology and Enzyme Catalysis, Institute of Biochemistry, Greifswald University, Felix-Hausdorff-Str. 4, 17487 Greifswald, Germany

  2. 3

    Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Biotecnología de Asturias, Universidad de Oviedo, Oviedo, Spain

  3. 4

    Center for Biocatalysis and Bioprocessing, 2501 Crosspark Road, MTF-Suite C100, The University of Iowa, Coralville, Iowa, USA, 52241-3486, USA

  4. 5

    Department of Chemistry, Organic and Bioorganic chemistry, University of Graz, Heinrichstraße -28, 8010 Graz, Austria

  5. 6

    Manchester Interdisciplinary Biocentre (MIB), The University of Manchester, 131 Princess Street, Manchester, M1 7DN, UK

Publication History

  1. Published Online: 13 MAY 2012
  2. Published Print: 11 MAY 2012

ISBN Information

Print ISBN: 9781119991397

Online ISBN: 9781119943426

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Keywords:

  • selective oxidation;
  • biocatalytic oxidative desymmetrization;
  • substituted pyrrolidines;
  • Baeyer–Villiger monooxygenase-catalyzed conversion;
  • optically active 3-alkyl-3-,4-dihydroioscoumarins;
  • dynamic kinetic resolutions;
  • oxidative cleavage of B-Ring;
  • alkene biocatalytic cleavage

Summary

This chapter contains sections titled:

  • Enantioselective Biocatalytic Oxidative Desymmetrization of Substituted Pyrrolidines

  • Large Scale Baeyer–Villiger Monooxygenase-Catalyzed Conversion of (R,S)-3-phenylbutan-2-one

  • Synthesis of Optically Active 3-Alkyl-3-,4-dihydroioscoumarins by Dynamic Kinetic Resolutions Catalyzed by a Baeyer–Villiger Monooxygenase

  • Oxidative Cleavage of the B-Ring of (+)Catechin

  • 18O-Isotopic Labeling in the Meta-Dioxygenase Cleavage of (+)-Catechin B-Ring

  • Biocatalytic Cleavage of Alkenes with Oxygen and Trametes hirsuta G FCC047