13. Supramolecular Assembly of Silver(I) Complexes with Argentophilic and Silver…Carbon Interactions

  1. Edward R. T. Tiekink3 and
  2. Julio Zukerman-Schpector4
  1. Thomas C. W. Mak,
  2. Liang Zhao and
  3. Xiao-Li Zhao

Published Online: 22 MAR 2012

DOI: 10.1002/9781119945888.ch13

The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering

The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering

How to Cite

Mak, T. C. W., Zhao, L. and Zhao, X.-L. (2012) Supramolecular Assembly of Silver(I) Complexes with Argentophilic and Silver…Carbon Interactions, in The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering (eds E. R. T. Tiekink and J. Zukerman-Schpector), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119945888.ch13

Editor Information

  1. 3

    Department of Chemistry, The University of Malaya, Kuala Lumpur, Malaysia

  2. 4

    Department of Chemistry, Federal University of São Carlos, São Carlos, Brazil

Author Information

  1. Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, P. R. China

Publication History

  1. Published Online: 22 MAR 2012
  2. Published Print: 30 MAR 2012

ISBN Information

Print ISBN: 9780470688274

Online ISBN: 9781119945888

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Keywords:

  • silver(I), with argentophilic and silver…carbon;
  • supramolecular assembly;
  • metallophilic interaction;
  • ethynide-containing, polyatomic anions;
  • three-dimensional structures;
  • polyhedral silver-ethynediide;
  • double/multiple salts;
  • silver(I)-alkynyl clusters

Summary

This chapter contains sections titled:

  • Introduction

  • Silver Double/Multiple Salts Containing Ag2C2

  • Supramolecular Assembly of Silver(I) Double/Triple Salts with Potentially Exo-Bidentate Ligands

  • Silver(I) Multiple Salts of 1,3-Butadiynediide (C42−)

  • Supramolecular Assembly with Silver tert-Butylethynide

  • Double/Multiple Salts of Silver Arylethynides

  • Assembly of Silver–Heteroaromatic Ethynide Supramolecular Synthons R[BOND]C[TRIPLE BOND]C⊃Agn (n = 4, 5) (R = Thienyl, Pyridyl, Pyrazinyl, Pyrimidyl)

  • Assembly of Silver–Ethynide Supramolecular Synthon Assisted by Silver…Aromatic Interaction

  • Assembly of Silver–Ethynide Supramolecular Synthon Assisted by Intermolecular Silver…Halogen Interaction

  • Coordination Networks Constructed of Multinuclear C2@Agn Aggregates and Polyoxometalate Species

  • Supramolecular Assembly of Large Silver–Ethynide Clusters

  • Conclusion and Outlook

  • Acknowledgments

  • References