6. Organic π-Radicals in the Solid-State: From Localised to Delocalised σ-Bonding

  1. Edward R. T. Tiekink2 and
  2. Julio Zukerman-Schpector3
  1. Marc Fourmigué

Published Online: 22 MAR 2012

DOI: 10.1002/9781119945888.ch6

The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering

The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering

How to Cite

Fourmigué, M. (2012) Organic π-Radicals in the Solid-State: From Localised to Delocalised σ-Bonding, in The Importance of Pi-Interactions in Crystal Engineering: Frontiers in Crystal Engineering (eds E. R. T. Tiekink and J. Zukerman-Schpector), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119945888.ch6

Editor Information

  1. 2

    Department of Chemistry, The University of Malaya, Kuala Lumpur, Malaysia

  2. 3

    Department of Chemistry, Federal University of São Carlos, São Carlos, Brazil

Author Information

  1. Institute of Chemistry, University of Rennes & CNRS UMR 6226, Rennes, France

Publication History

  1. Published Online: 22 MAR 2012
  2. Published Print: 30 MAR 2012

ISBN Information

Print ISBN: 9780470688274

Online ISBN: 9781119945888

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Keywords:

  • organic π-radicals, solid-state;
  • localised to delocalised σ-bonding;
  • density probability, of SOMO;
  • π-radical formation;
  • noninnocent ligands;
  • dimers of radicals;
  • dimmers, pimers in solid state;
  • π-type orbital

Summary

This chapter contains sections titled:

  • Introduction

  • Molecules for π-Radical Formation

  • Dimers of Radicals versus Radical Dimers (Pimers)

  • Solid-State Magnetic and Conducting Properties

  • Conclusions

  • Acknowledgments

  • References