2. Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch2

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

How to Cite

Temkin, O. N. (2012) Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch2

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227

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Keywords:

  • metal complexes' reactions, functions of catalysts, reactants;
  • catalysis with metal complexes in homogeneous, and material balance;
  • mononuclear metal complexes;
  • complexity functions, variants I and II, and III and IV;
  • intermediate products, complexity functions (FM, FS) in kinetic equations;
  • formulating hypotheses, structure of complexity, experiments discriminating them;
  • investigation of kinetics of butylacrylate synthesis;
  • kinetic model construction, material balance for metal complexes, substrates;
  • ways of discrimination, between hypotheses;
  • uniformity, nonuniformity of active centers, not a basis, definitions of homo-, heterogeneous catalysis

Summary

This chapter contains sections titled:

  • Mononuclear metal complexes

  • Polynuclear complexes in homogeneous catalytic and noncatalytic reactions

  • Catalysis with polynuclear copper(I) halide complexes in superconcentrated solutions

  • References