4. Polyfunctional Catalytic Systems

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch4

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

How to Cite

Temkin, O. N. (2012) Polyfunctional Catalytic Systems, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch4

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227



  • PFCSs, and kinetic polyfunctionality, representing systems of catalysts;
  • MCSs, chemical and kinetic functions, the chemical polyfunctionality;
  • kinetic polyfunctionality, MCSs, and KFs as catalysts, blocks of steps;
  • oxidation reactions of organic, inorganic, two- and three-component PFCSs;
  • KFs, polyfunctional catalytic system, CuCl2 –I2, and MCSs, group B;
  • oxidation of 1,3-dienes in solutions of MCSs, variants of polyfunctionality;
  • oxidative chlorination, alkyne conversion by kinetic, chemical methods;
  • PFCSs, principles, polyfunctional catalytic systems in chlorination reactions;
  • multicomponent PFCSs, reactions of hydrogen ion substitution;
  • multicomponent reactions, unstable intermediates as with polyfunctionality


This chapter contains sections titled:

  • Oxidation reactions of organic and inorganic compounds

  • Reactions of chlorination and oxidative chlorination of organic compounds

  • Oxidative carbonylation of organic compounds

  • Additive carbonylation of alkynes, alkenes, dienes, and alcohols

  • Substitution and addition reactions in alkyne chemistry

  • General problems in PFCS theory and practice

  • References