5. Mechanisms of Formation of Catalytically Active Metal Complexes

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch5

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

How to Cite

Temkin, O. N. (2012) Mechanisms of Formation of Catalytically Active Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch5

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227

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Keywords:

  • catalytically active metal complexes, mechanisms of formation;
  • heterogeneous catalysis with metals and their oxides;
  • kinetics of heterogeneous catalytic reactions, catalytically active centers;
  • catalytic stages, Pd(I) carbonyl halide complexes;
  • mechanism, formation of catalytically active complexes;
  • catalytic process, and protecting active centers, from destruction;
  • giant palladium clusters, pathways of synthesis of unusual compounds;
  • identification of nature of catalytically active species, metal complexes;
  • criteria, discrimination of hypotheses of catalysis with molecular complexes;
  • chain mechanisms in real catalytic, and active kinetic chain carrier

Summary

This chapter contains sections titled:

  • Main stages of catalytic process

  • Chemical reactions involved in the formation of active centers

  • Mechanisms of active center formation in particular processes

  • Examples of chain mechanisms and chain carriers of various natures

  • Classification of mechanisms of real catalytic processes

  • References