6. Nonlinear Effects (Critical Phenomena) in Reaction Dynamics in Homogeneous Catalysis with Metal Complexes

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch6

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

How to Cite

Temkin, O. N. (2012) Nonlinear Effects (Critical Phenomena) in Reaction Dynamics in Homogeneous Catalysis with Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch6

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227

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Keywords:

  • nonlinear effects in reaction dynamics, homogeneous, with metal complexes;
  • kinetics and mechanisms of homogeneous reactions, of metal complexes;
  • nonlinear approaches in heterogeneous catalysis;
  • physicochemical factors, phenomena in homogeneous reactions;
  • thermodynamics of irreversible processes, stability of steady states;
  • nonlinear systems and thermodynamic stability, of dynamical systems;
  • kinetic graph of mechanism of substrate-inhibited reaction;
  • dimensionality of kinetic model, and critical phenomena;
  • mechanisms, kinetic models of reactions catalyzed by metal complexes;
  • “nonlinear view” on kinetics, catalytic reaction mechanisms

Summary

This chapter contains sections titled:

  • Historical notes

  • Physicochemical factors responsible for the critical phenomena in homogeneous reactions

  • Analysis of simple nonlinear kinetic models

  • Mechanisms of oscillatory catalytic reactions

  • References