6. Nonlinear Effects (Critical Phenomena) in Reaction Dynamics in Homogeneous Catalysis with Metal Complexes

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch6

Book Title

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Additional Information

How to Cite

Temkin, O. N. (2012) Nonlinear Effects (Critical Phenomena) in Reaction Dynamics in Homogeneous Catalysis with Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch6

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227

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CHAPTER TOOLS

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Keywords:

  • nonlinear effects in reaction dynamics, homogeneous, with metal complexes;
  • kinetics and mechanisms of homogeneous reactions, of metal complexes;
  • nonlinear approaches in heterogeneous catalysis;
  • physicochemical factors, phenomena in homogeneous reactions;
  • thermodynamics of irreversible processes, stability of steady states;
  • nonlinear systems and thermodynamic stability, of dynamical systems;
  • kinetic graph of mechanism of substrate-inhibited reaction;
  • dimensionality of kinetic model, and critical phenomena;
  • mechanisms, kinetic models of reactions catalyzed by metal complexes;
  • “nonlinear view” on kinetics, catalytic reaction mechanisms

Summary

This chapter contains sections titled:

  • Historical notes

  • Physicochemical factors responsible for the critical phenomena in homogeneous reactions

  • Analysis of simple nonlinear kinetic models

  • Mechanisms of oscillatory catalytic reactions

  • References

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