8. Effect of Medium on Reaction Rates in Homogeneous Catalysis with Metal Complexes
Published Online: 4 JAN 2012
DOI: 10.1002/9781119966227.ch8
Copyright © 2012 John Wiley & Sons, Ltd
Book Title
Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms
Additional Information
How to Cite
Temkin, O. N. (2012) Effect of Medium on Reaction Rates in Homogeneous Catalysis with Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch8
Publication History
- Published Online: 4 JAN 2012
- Published Print: 16 MAR 2012
ISBN Information
Print ISBN: 9780470666999
Online ISBN: 9781119966227
- Summary
- Chapter
- References
Keywords:
- homogeneous catalysis with metal complexes, medium and reaction rates;
- kinetic experiments in aqueous, organic systems;
- maintaining constant activity coefficients;
- electrolytes on solubility of gases, organic substances;
- salting-out effect, and low electrolyte concentrations;
- organic solvents in homogeneous catalysis with metal complexes;
- inner-sphere coordination of solvent (S) molecules, all metals in groups I, II, III;
- ionic liquids in catalytic chemistry;
- supercritical fluid in homogeneous catalysis, and catalyst activity control
Summary
This chapter contains sections titled:
Effect of electrolytes on the activity coefficients of reaction medium components
Effect of electrolytes on the solubility of nonelectrolytes (gases and organic compounds)
Effect of electrolytes on the rates of elementary reactions between ions and uncharged substrates
Kinetics of catalytic reactions in concentrated aqueous electrolyte (HCl) solutions
Organic solvents in homogeneous catalysis with metal complexes
Strong protonic acids in organic solvents and kinetics of catalytic reactions with metal complexes in these media
Ionic liquids in catalytic chemistry
References