8. Effect of Medium on Reaction Rates in Homogeneous Catalysis with Metal Complexes

  1. O. N. Temkin

Published Online: 4 JAN 2012

DOI: 10.1002/9781119966227.ch8

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms

How to Cite

Temkin, O. N. (2012) Effect of Medium on Reaction Rates in Homogeneous Catalysis with Metal Complexes, in Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9781119966227.ch8

Author Information

  1. M.V. Lomonosov Moscow State University of Fine Chemical Technology, Russia

Publication History

  1. Published Online: 4 JAN 2012
  2. Published Print: 16 MAR 2012

ISBN Information

Print ISBN: 9780470666999

Online ISBN: 9781119966227

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Keywords:

  • homogeneous catalysis with metal complexes, medium and reaction rates;
  • kinetic experiments in aqueous, organic systems;
  • maintaining constant activity coefficients;
  • electrolytes on solubility of gases, organic substances;
  • salting-out effect, and low electrolyte concentrations;
  • organic solvents in homogeneous catalysis with metal complexes;
  • inner-sphere coordination of solvent (S) molecules, all metals in groups I, II, III;
  • ionic liquids in catalytic chemistry;
  • supercritical fluid in homogeneous catalysis, and catalyst activity control

Summary

This chapter contains sections titled:

  • Effect of electrolytes on the activity coefficients of reaction medium components

  • Effect of electrolytes on the solubility of nonelectrolytes (gases and organic compounds)

  • Effect of electrolytes on the rates of elementary reactions between ions and uncharged substrates

  • Kinetics of catalytic reactions in concentrated aqueous electrolyte (HCl) solutions

  • Organic solvents in homogeneous catalysis with metal complexes

  • Strong protonic acids in organic solvents and kinetics of catalytic reactions with metal complexes in these media

  • Ionic liquids in catalytic chemistry

  • References