Chapter 18. Topospecific Chemistry at Surfaces

  1. Deutsche Forschungsgemeinschaft (DFG)
  1. Hans Ludwig Krauss

Published Online: 21 DEC 2006

DOI: 10.1002/9783527609284.ch18

Macromolecular Systems: Microscopic Interactions and Macroscopic Properties: Final Report

Macromolecular Systems: Microscopic Interactions and Macroscopic Properties: Final Report

How to Cite

Krauss, H. L. (2000) Topospecific Chemistry at Surfaces, in Macromolecular Systems: Microscopic Interactions and Macroscopic Properties: Final Report (ed Deutsche Forschungsgemeinschaft (DFG)), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527609284.ch18

Author Information

  1. Heunischstraße 5 b, 96049 Bamberg, Germany

Publication History

  1. Published Online: 21 DEC 2006
  2. Published Print: 13 JUL 2000

ISBN Information

Print ISBN: 9783527277261

Online ISBN: 9783527609284

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Keywords:

  • macromolecular systems;
  • topospecific chemistry at surfaces;
  • Phillips process

Summary

This chapter contains sections titled:

  • Introduction

    • The problem

    • Preparative and analytical methods

    • Industrial applications

    • The standard procedures of the Phillips process

    • Earlier work

  • The support

    • Unmodified silica

    • Modified silica

    • Others

  • Transition metal surface compounds

    • The metals

    • Impregnation and activation

  • Coordinatively unsaturated sites

    • Reduction of saturated surface compounds

    • Elimination of ligands

  • Physical properties of the coordinatively unsaturated sites

    • Topologically different sites

    • Optical and magnetic properties

  • Chemical properties of the coordinatively unsaturated sites

    • Survey of catalytic reactions

    • Olefin polymerization

    • Other catalytic reactions

  • Deactivation

  • Summary and outlook

  • References