Chapter 11. Combustion Propagation of Pyrolants

  1. Prof. Dr. Naminosuke Kubota

Published Online: 5 JAN 2007

DOI: 10.1002/9783527610105.ch11

Propellants and Explosives: Thermochemical Aspects of Combustion, Second Edition

Propellants and Explosives: Thermochemical Aspects of Combustion, Second Edition

How to Cite

Kubota, N. (2007) Combustion Propagation of Pyrolants, in Propellants and Explosives: Thermochemical Aspects of Combustion, Second Edition, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527610105.ch11

Author Information

  1. Asahi Kasei Chemicals, Propellant Combustion Laboratory, Arca East, Kinshi 3-2-1, Sumidaku, Tokyo 130-6591, Japan

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 20 OCT 2006

ISBN Information

Print ISBN: 9783527314249

Online ISBN: 9783527610105

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Keywords:

  • propellants;
  • explosives;
  • combustion propagation of pyrolants;
  • physicochemical structures of combustion waves;
  • combustion of metal particles;
  • black powder;
  • Li-SF6 pyrolants;
  • Zr pyrolants;
  • Mg-Tf pyrolants;
  • B-KNO3 pyrolants;
  • Ti-KNO3 pyrolants;
  • Zr-KNO3 pyrolants;
  • metal-GAP pyrolants;
  • Ti-C pyrolants;
  • NaN3 pyrolants;
  • GAP-AN pyrolants;
  • nitramine pyrolants;
  • B-AP pyrolants;
  • friction sensitivity of pyrolants

Summary

This chapter contains sections titled:

  • Physicochemical Structures of Combustion Waves

    • Thermal Decomposition and Heat Release Process

    • Homogeneous Pyrolants

    • Heterogeneous Pyrolants

    • Pyrolants as Igniters

  • Combustion of Metal Particles

    • Oxidation and Combustion Processes

      • Aluminum Particles

      • Magnesium Particles

      • Boron Particles

      • Zirconium Particles

  • Black Powder

    • Physicochemical Properties

    • Reaction Process and Burning Rate

  • Li-SF6 Pyrolants

    • Reactivity of Lithium

    • Chemical Characteristics of SF6

  • Zr Pyrolants

    • Reactivity with BaCrO4

    • Reactivity with Fe2O3

  • Mg-Tf Pyrolants

    • Thermochemical Properties and Energetics

    • Reactivity of Mg and Tf

    • Burning Rate Characteristics

    • Combustion Wave Structure

  • B-KNO3 Pyrolants

    • Thermochemical Properties and Energetics

    • Burning Rate Characteristics

  • Ti-KNO3 and Zr-KNO3 Pyrolants

    • Oxidation Process

    • Burning Rate Characteristics

  • Metal-GAP Pyrolants

    • Flame Temperature and Combustion Products

    • Thermal Decomposition Process

    • Burning Rate Characteristics

  • Ti-C Pyrolants

    • Thermochemical Properties of Titanium and Carbon

    • Reactivity of Tf with Ti-C Pyrolants

    • Burning Rate Characteristics

  • NaN3 Pyrolants

    • Thermochemical Properties of NaN3 Pyrolants

    • NaN3 Pyrolant Formulations

    • Burning Rate Characteristics

    • Combustion Residue Analysis

  • GAP-AN Pyrolants

    • Thermochemical Characteristics

    • Burning Rate Characteristics

    • Combustion Wave Structure and Heat Transfer

  • Nitramine Pyrolants

    • Physicochemical Properties

    • Combustion Wave Structures

  • B-AP Pyrolants

    • Thermochemical Characteristics

    • Burning Rate Characteristics

    • Burning Rate Analysis

    • Site and Mode of Boron Combustion in the Combustion Wave

  • Friction Sensitivity of Pyrolants

    • Definition of Friction Energy

    • Effect of Organic Iron and Boron Compounds