Chapter 12. The State of the Art and Perspectives in Catalysis by Heterogenized Polymer-Bound Metal Complexes

  1. Prof. Dr. Dieter Wöhrle1 and
  2. Prof. Dr. Anatolii D. Pomogailo2
  1. Prof. Dr. Anatolii Pomogailo

Published Online: 3 DEC 2007

DOI: 10.1002/9783527610778.ch12

Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties

Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties

How to Cite

Pomogailo, A. (2003) The State of the Art and Perspectives in Catalysis by Heterogenized Polymer-Bound Metal Complexes, in Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties (eds D. Wöhrle and A. D. Pomogailo), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527610778.ch12

Editor Information

  1. 1

    Institute of Organic and Macromolecular Chemistry, University of Bremen, P.O. Box 330 440, 28334 Bremen, Germany

  2. 2

    Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chemogolovka, Moscow Region, 142432, Russia

Author Information

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chemogolovka, Moscow Region, 142432, Russia

Publication History

  1. Published Online: 3 DEC 2007
  2. Published Print: 12 MAY 2003

ISBN Information

Print ISBN: 9783527304998

Online ISBN: 9783527610778

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Keywords:

  • properties;
  • catalysis by heterogenized polymer-bound metal complexes;
  • state of the art;
  • perspectives;
  • place of polymer-immobilized metal complexes;
  • features of hydrogenation reactions;
  • general kinetic regularities;
  • macromolecular complexes initiating polymerization processes;
  • oxidation catalysis;
  • role of metal ions in oxidation;
  • hydroformylation in the presence of polymer-immobilized metal complexes

Summary

This chapter contains sections titled:

  • The Place of Polymer-Immobilized Metal Complexes in Catalysis

  • The Features of Hydrogenation Reactions Catalyzed by Macromolecular Metal Complexes

    • General Kinetic Regularities

    • The Influence of the Nature of a Metal Complex on Its Catalytic Properties

    • Formation of Coordinatively Unsaturated and Isolated Complexes

    • The Influence of Solvent Properties

    • The Influence of Reaction Temperature

    • Surface Density

    • Size Effects in Hydrogenation by Polymer-Immobilized Complexes

    • Problems of Selectivity in Hydrogenation Reactions Catalyzed by Macromolecular Metal Complexes

    • Perspectives in the Development of Hydrogenation Catalysis by Macromolecular Complexes

  • Polymerization Processes Initiated by Macromolecular Complexes

    • Peculiarities of Olefin Polymerization

    • Ethylene Polymerization by Titanium–Magnesium Catalysts

    • Gel-Immobilized Systems

    • Stereospecific Propylene Polymerization

    • The Heterogenization of Homogeneous Metallocene Catalysts for Olefin Polymerization

    • Polymerization of Vinyl Monomers in the Presence of Macromolecular Complexes

    • Other Perspectives in Polymerization Catalysis by Macromolecular Complexes

  • Oxidation Catalysis in the Presence of Macromolecular Complexes

    • The Role of Metal Ions in Oxidation

    • Reactions of Hydrocarbon Oxidation by Oxygen

    • Peroxide Oxidation of Alkylarenes and Hydroxyarenes

    • Catalysis of Olefin Epoxidation by Alkylhydroperoxides

    • Catalytic Oxidation of Oxygen-Containing Substrates and Prospects for Oxidation Catalysis

  • Hydroformylation in the Presence of Polymer-Immobilized Metal Complexes

    • Hydroformylation of Olefins

    • Problems of Polyfunctional Catalysis by Immobilized Metal Complexes

    • Asymmetric Hydroformylation Reactions

    • Other Prospective Oxo-Processes

  • Conclusion

  • Experimental

  • References