Chapter 4. Polymerization of Metal-Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules

  1. Prof. Dr. Dieter Wöhrle1 and
  2. Prof. Dr. Anatolii D. Pomogailo2
  1. Prof. Dr. Anatolii Pomogailo

Published Online: 3 DEC 2007

DOI: 10.1002/9783527610778.ch4

Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties

Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties

How to Cite

Pomogailo, A. (2003) Polymerization of Metal-Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules, in Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties (eds D. Wöhrle and A. D. Pomogailo), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527610778.ch4

Editor Information

  1. 1

    Institute of Organic and Macromolecular Chemistry, University of Bremen, P.O. Box 330 440, 28334 Bremen, Germany

  2. 2

    Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chemogolovka, Moscow Region, 142432, Russia

Author Information

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chemogolovka, Moscow Region, 142432, Russia

Publication History

  1. Published Online: 3 DEC 2007
  2. Published Print: 12 MAY 2003

ISBN Information

Print ISBN: 9783527304998

Online ISBN: 9783527610778

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Keywords:

  • synthesis;
  • structures;
  • polymerization of metal-containing monomers (MCMs);
  • incorporating metals in macromolecules;
  • MCM classification;
  • different methods of synthesis of MCMs;
  • homopolymerization of metal-containing monomers;
  • MCM copolymerization;
  • future development;
  • experimental

Summary

This chapter contains sections titled:

  • MCM Classification

  • Overview of the Different Methods of Synthesis of MCMs

    • Synthesis of σ-MCMs of the Organometallic Type

    • σ-Type Organoelemental Monomers

    • Ionic-type MCMs

    • nv-Type MCMs

    • π-Type Metal-Containing Monomers

    • Polymerizable Chelate-Type MCMs

    • MCMs with Macrocyclic Chelate Nodes

    • Polynuclear and Cluster MCMs

  • Homopolymerization of Metal-Containing Monomers

    • The Specific Character of the Homopolymerization of True Organometallic Monomers

    • Homopolymerization of Organoelemental Monomers

    • Radical Polymerization of Salts of Unsaturated Carboxylic Acids

    • Homopolymerization of nv-Type MCMs

    • Frontal Polymerization of Acrylamide Complexes

    • Homopolymerization of π-Type MCMs

    • Polymerization of Chelate-Type MCMs

  • MCM Copolymerization

    • Organometallic Monomers in Copolymerization Reactions

    • Copolymerization of Ionic-Type MCMs

    • Peculiarities of Copolymerization of Donor-Acceptor Type MCMs

    • Copolymerization of π-MCMs

    • Chelate-Type Monomers in Copolymerization with Conventional Monomers

    • Mutual MCM Copolymerization

    • Copolymerization of Cluster-Containing Monomers

  • The Future Development of Polymerization and Copolymerization of MCMs

  • Experimental

  • References