Chapter 7. Catalysis in Novel Reaction Media

  1. Prof. Dr. Roger Arthur Sheldon,
  2. Dr. Isabel W. C. E. Arends and
  3. Dr. Ulf Hanefeld

Published Online: 12 APR 2007

DOI: 10.1002/9783527611003.ch7

Green Chemistry and Catalysis

Green Chemistry and Catalysis

How to Cite

Sheldon, R. A., Arends, I. W. C. E. and Hanefeld, U. (2007) Catalysis in Novel Reaction Media, in Green Chemistry and Catalysis, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527611003.ch7

Author Information

  1. Biocatalysis and Organic Chemistry, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands

Publication History

  1. Published Online: 12 APR 2007
  2. Published Print: 23 FEB 2007

ISBN Information

Print ISBN: 9783527307159

Online ISBN: 9783527611003

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Keywords:

  • catalysis in novel reaction media;
  • choice of solvent;
  • two immiscible organic solvents;
  • aqueous biphasic catalysis;
  • fluorous biphasic catalysis;
  • supercritical carbon dioxide;
  • supercritical fluids;
  • ionic liquids;
  • biphasic systems with supercritical carbon dioxide;
  • thermoregulated biphasic catalysis

Summary

This chapter contains sections titled:

  • Introduction

    • Why use a solvent?

    • Choice of Solvent

    • Alternative Reaction Media and Multiphasic Systems

  • Two Immiscible Organic Solvents

  • Aqueous Biphasic Catalysis

    • Olefin Hydroformylation

    • Hydrogenation

    • Carbonylations

    • Other C–C Bond Forming Reactions

    • Oxidations

  • Fluorous Biphasic Catalysis

    • Olefin Hydroformylation

    • Other Reactions

  • Supercritical Carbon Dioxide

    • Supercritical Fluids

    • Supercritical Carbon Dioxide

    • Hydrogenation

    • Oxidation

    • Biocatalysis

  • Ionic Liquids

  • Biphasic Systems with Supercritical Carbon Dioxide

  • Thermoregulated Biphasic Catalysis

  • Conclusions and Prospects