Chapter 2. Cathode Active Materials with a Three-dimensional Spinel Framework

  1. Professor M. Wakihara2 and
  2. O. Yamamoto3
  1. M. Wakihara,
  2. Guohua Li and
  3. H. Ikuta

Published Online: 20 DEC 2007

DOI: 10.1002/9783527612000.ch2

Lithium Ion Batteries: Fundamentals and Performance

Lithium Ion Batteries: Fundamentals and Performance

How to Cite

Wakihara, M., Li, G. and Ikuta, H. (1998) Cathode Active Materials with a Three-dimensional Spinel Framework, in Lithium Ion Batteries: Fundamentals and Performance (eds M. Wakihara and O. Yamamoto), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527612000.ch2

Editor Information

  1. 2

    Department of Chemical Engineering, Tokyo Institute of Technology, Tokyo 152, Japan

  2. 3

    Department of Chemistry, Mie University, Tsu-shi, Mie 514, Japan

Author Information

  1. Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152, Japan

Publication History

  1. Published Online: 20 DEC 2007
  2. Published Print: 12 JUN 1998

ISBN Information

Print ISBN: 9783527295692

Online ISBN: 9783527612000

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Keywords:

  • “rocking-chair”;
  • (cluster compound, M = metal);
  • (M = Co, Cr and Ni);
  • (PTFE);
  • OCV and phase transformation

Summary

This chapter contains sections titled:

  • Introduction

  • Crystal Structure of Spinel Type Phases

  • Synthesis Technique

  • Relationship between Discharge Voltage and Thermodynamic Function of the Cathode Materials

  • Phase Transformation During Intercalation Processes

  • Doped Spinel Phases LiMy,Mn2-y O4 (M = Co, Cr, Ni) as 4 V-Class Cathode Material

  • Conclusions