Chapter I. Organosilicon-Based Reactive Intermediates

  1. Prof. Dr. Norbert Auner1 and
  2. Prof. Dr. Johann Weis2

Published Online: 21 MAY 2008

DOI: 10.1002/9783527618224.ch1

Organosilicon Chemistry VI: From Molecules to Materials

Organosilicon Chemistry VI: From Molecules to Materials

How to Cite

Auner, N. and Weis, J. (eds) (2005) Organosilicon-Based Reactive Intermediates, in Organosilicon Chemistry VI: From Molecules to Materials, Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618224.ch1

Editor Information

  1. 1

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 2

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Publication History

  1. Published Online: 21 MAY 2008
  2. Published Print: 26 JUL 2005

ISBN Information

Print ISBN: 9783527312146

Online ISBN: 9783527618224



  • silylene chemistry;
  • diazoalkanes;
  • photoextrusion;
  • dimethylbutadiene;
  • bicycloheptatriene


The chapter contains sections titled:

  • Learning from Silylenes and Supersilylenes

  • New Molecular Systems with Silicon-Silicon Multiple Bonds

  • 1-[2,6-Bis(dimethylaminomethyl)phenyl]-2,2- bis(trimethylsilyl)silenes – Syntheses, Structures, and Reactions

  • Quantum Chemical DFT and Experimental Study of ortho-, metha-, and/para-Tolyl-Substituted Methylsilene Rearrangements

  • A 1,4 Disilapentalene and a Highly Stable Silicon Diradical

  • Kinetic Stabilization of Polysilyl Radicals

  • Out-of-Range δ29Si Chemical Shifts of Diaminosilylenes – an ab initio Study

  • Comparison of Heterocyclic Diaminosilylenes with Their Group 14 Homologs

  • Spectroscopic Evidence for the Formation of the Pentamethylcyclopentadienylsilicon Cation

  • Synthesis and Characterization of Bissilyiated Onium Ions of Group 15 Elements

  • Structural and Spectroscopic Evidence for β-SiC Hyperconjugation in Vinyl Cations

  • Tertiary Trisilyloxonium Ion and Silylenium Cation in Cationic Ring-Opening Polymerization of Cyclic Siloxanes