Chapter II. Molecular Incorganic Silicon Chemistry - Part 2

  1. Prof. Dr. Norbert Auner1 and
  2. Prof. Dr. Johann Weis2

Published Online: 21 MAY 2008

DOI: 10.1002/9783527618224.ch2b

Organosilicon Chemistry VI: From Molecules to Materials

Organosilicon Chemistry VI: From Molecules to Materials

How to Cite

Auner, N. and Weis, J. (eds) (2005) Molecular Incorganic Silicon Chemistry - Part 2, in Organosilicon Chemistry VI: From Molecules to Materials, Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618224.ch2b

Editor Information

  1. 1

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 2

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Publication History

  1. Published Online: 21 MAY 2008
  2. Published Print: 26 JUL 2005

ISBN Information

Print ISBN: 9783527312146

Online ISBN: 9783527618224

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Keywords:

  • silicon amidinates;
  • germanium amidinates;
  • hypervalency;
  • low-valency

Summary

The chapter contains sections titled:

  • “Hypervalent” Molecules – Low-Valency Candidates for Materials?

  • Strong Evidence for an Unconventional 1,2-(C[RIGHTWARDS ARROW]P)-Silyl Migration: Formation and Reactions of a P-Silyl Phosphaalkene Complex

  • Strong Evidence for an Unconventional 1,2-(C[RIGHTWARDS ARROW]P)-Silyl Migration: DFT Structures and Bond Strengths (Compliance Constants)

  • Silyl Group Migrations between Oxygen and Nitrogen in Aminosiloxanes

  • Terphenyl Phosphanosilanes

  • Preparations and X-Ray Structures of Some Silicon-Phosphorus and Silicon-Arsenic Cages

  • Homo- and Heterometallic Bismuth Silanolates

  • The Effect of Silyl Anion Substituents on the Stability and NMR Characteristics of Cyclic Polyphosphines - an ab initio/NMR Study

  • Silanols as Precursors to Cyclo- and Polysiloxanes

  • The Origin of Ring Strain and Conformational Flexibility in Tri- and Tetrasiloxane Rings and Their Heavier Group 14 Congeners

  • 29Si NMR Chemical Shift Tensors in Organosilicon Chalcogenides

  • Hypersilyltelhiro-substituted Silanes and (Ph2SiTe)3

  • Novel Dimeric Pentacoordinate Silicon Complexes: Unusual Reactivity of Electron-Rich Aminosilane Intermediates

  • Unique Switching of Coordination Number with Imine and Enamine Complexes of Group 14 Elements