Chapter III. Transition Metals in Organosilicon-Based Chemistry

  1. Prof. Dr. Norbert Auner1 and
  2. Prof. Dr. Johann Weis2

Published Online: 21 MAY 2008

DOI: 10.1002/9783527618224.ch3

Organosilicon Chemistry VI: From Molecules to Materials

Organosilicon Chemistry VI: From Molecules to Materials

How to Cite

Auner, N. and Weis, J. (eds) (2005) Transition Metals in Organosilicon-Based Chemistry, in Organosilicon Chemistry VI: From Molecules to Materials, Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618224.ch3

Editor Information

  1. 1

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 2

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Publication History

  1. Published Online: 21 MAY 2008
  2. Published Print: 26 JUL 2005

ISBN Information

Print ISBN: 9783527312146

Online ISBN: 9783527618224



  • metal silyl;
  • metal silylene;
  • hydrosilation


The chapter contains sections titled:

  • Transition Metals in Organosilicon-Based Chemistry

  • Hydrosilation (or is it Hydrosilylation?): A Personal Perspective on a Scientifically and Technologically Fascinating Chemical Methodology

  • DFT Calculations on the Activation of Silanes by Platinum Complexes with Hemilabile P, N Ligands

  • Hydrosilylation of Ethylene, Cyclohexene, and Allyl Chloride in the Presence of Pt(0) and Pt(2) Catalysts

  • Synthesis of Glycidoxypropyl-Silanes and -Siloxanes via Rhodium Siloxide-Catalyzed Hydrosilylation

  • New Functionalization of Vinyl-Substituted Organosilicon Compounds via Ru-Catalyzed Reactions

  • Hydrosilylation Using Ionic Liquids

  • On-Line FT-Raman Spectroscopy for Process Control of the Hydrosilylation Reaction

  • [2+2]-Cycloadditions of (OC)4Fe=SiMe2 – Theoretical Study

  • Reactions of Undecamethylcydohexasilyl-potassium with Transition Metal Compounds

  • Cp-Free Hafnium Silyl Substituted Compounds

  • Metal- and Cyclopentadienyl-Bound Silanol Groups in Tungsten Complexes

  • Half-Sandwich Iron Complexes with a Silanol-Functionalized Cyclopentadienyl Ligand

  • Synthesis and Reactivity of Polychlorinated Metallo-Siloxanes

  • Half-Sandwich Tungsten Complexes with Silyl-Functionalized η5-Cyclopentadienyl Ligand