Chapter 2.7. The Radical-Polar Crossover Reaction

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. John A. Murphy

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch15

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Murphy, J. A. (2001) The Radical-Polar Crossover Reaction, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch15

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293



  • radical-polar crossover reaction;
  • oxidized sulfide;
  • tetrathiafulvalene;
  • arenediazonium;
  • sulfonium sulfur


The prelims comprise:

  • Concept and Discovery

  • Application to Preparation of Nitrogen Heterocycles

  • Neighboring Group Participation in the Solvolysis Stage

  • C-Linked Tetrathiafulvalenium Salts

  • Modified TTF Reagents

  • Acknowledgements