Chapter 2.2. Oxidation (Hydroxylation and Acyloxylation) via C-H Bond Activation

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. Tsutomu Katsuki

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch32

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Katsuki, T. (2001) Oxidation (Hydroxylation and Acyloxylation) via C-H Bond Activation, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch32

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293



  • acyloxylation;
  • carbon-heteroatom bond;
  • stereochemistry;
  • hydrogen atom abstraction;
  • hydroxylation


The prelims comprise:

  • Introduction

  • C-H Hydroxylation Using Metallo-Porphyrin and -Salen Complexes as Catalysts: its Mechanism and Stereochemistry

  • Kharasch-Sosnovsky Type of Allylic C-H Oxidation: its Mechanism and Stereocontrol

  • Conclusion