Chapter 3.2. Radical Rearrangements of Esters

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. David Crich

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch35

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Crich, D. (2001) Radical Rearrangements of Esters, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch35

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293



  • allyl radicals;
  • proton transfer;
  • alkyl migration;
  • nucleosides;
  • allyltributylstannane


The prelims comprise:

  • Introduction

  • Mechanism

  • Rearrangements and their Applications in Synthesis

  • Substitution Reactions and their Applications in Synthesis

  • Fragmentations

  • Thiocarbonyl Esters