Chapter 3.6. Hydrogen Atom Abstraction

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. Laurence Feray,
  2. Nikolai Kuznetsov and
  3. Philippe Renaud

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch39

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Feray, L., Kuznetsov, N. and Renaud, P. (2008) Hydrogen Atom Abstraction, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch39

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293

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Keywords:

  • hydrogen atom abstraction;
  • thermochemistry;
  • alkoxy radicals;
  • peroxides;
  • carbon-carbon bond

Summary

The prelims comprise:

  • Introduction

  • Alkoxyl Radical

  • Aminyl Radical: Hofmann-Löffler-Freytag Reaction

  • Thiyl Radicals

  • Complexed Chlorine Radicals

  • Alkyl Radicals

  • Perhaloalkyl Radicals

  • Aryl Radicals: Protecting/Radical-Translocating Groups

  • Alkenyl Radicals

  • Diastereoselectivity of Hydrogen Atom Abstraction

  • Conclusions