Chapter 4.3. Utilization of α-Oxygenated Radicals in Synthesis

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. Alexandre J. Buckmelter and
  2. Scott D. Rychnovsky

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch42

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Buckmelter, A. J. and Rychnovsky, S. D. (2001) Utilization of α-Oxygenated Radicals in Synthesis, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch42

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293



  • oxygenated radicals;
  • carbohydrate;
  • pyranose radicals;
  • lithiations;
  • glucopyranoside


The prelims comprise:

  • Introduction

  • Conformation and Stereoelectronic Effects of Cyclic α-Oxygenated Radicals

  • Generation of α-Oxygenated Radicals and their Subsequent Reactions

  • Non-Equilibrium Radical Reactions

  • Conformational Memory of Radical Intermediates

  • Conclusions