Chapter 5.3. β-Fragmentation of Alkoxyl Radicals: Synthetic Applications

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. Ernesto Suárez and
  2. Maria S. Rodriguez

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch47

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Suárez, E. and Rodriguez, M. S. (2008) β-Fragmentation of Alkoxyl Radicals: Synthetic Applications, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch47

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293

SEARCH

Keywords:

  • homolytic cleavage;
  • cyclopentane;
  • acyclic alkoxyl radicals;
  • alkyl hydroperoxides;
  • hemiacetals

Summary

The prelims comprise:

  • Introduction

  • Synthetic Methods

  • Fragmentation of Alkoxyl Radicals Generated under Oxidative Conditions

  • Fragmentation of Alkoxyl Radicals Generated under Reductive Conditions

  • Conclusion

  • Acknowledgement