Chapter 2.1. Samarium(II) Mediated Radical Reactions

  1. Prof. Philippe Renaud1 and
  2. Prof. Mukund P. Sibi2
  1. Gary A. Molander

Published Online: 26 MAR 2008

DOI: 10.1002/9783527618293.ch9

Radicals in Organic Synthesis

Radicals in Organic Synthesis

How to Cite

Molander, G. A. (2001) Samarium(II) Mediated Radical Reactions, in Radicals in Organic Synthesis (eds P. Renaud and M. P. Sibi), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527618293.ch9

Editor Information

  1. 1

    Universite de Fribourg, Institut de Chimie Organique, Pérolles, CH-1700 Fribourg, Switzerland

  2. 2

    Department of Chemistry, North Dakota State University, Fargo, ND 58105, USA

Publication History

  1. Published Online: 26 MAR 2008
  2. Published Print: 29 MAR 2001

ISBN Information

Print ISBN: 9783527301607

Online ISBN: 9783527618293



  • alkenyl radical reactions;
  • alkenes;
  • diphenylhedrazones;
  • glycosyl precursor;
  • benzotriazolyl anion


The prelims comprise:

  • Introduction

  • Alkyl, Aryl, and Alkenyl Radical Addition Reactions

  • Pinacol and Related Coupling Reactions

  • Ketyl Addition Reactions

  • Hydrodimerization Reactions

  • Radical Fragmentation Reactions

  • Miscellaneous Radical Reactions

  • Conclusions

  • Acknowledgements