Chapter 10. Palladium-Catalyzed Coupling Reactions of Propargyl Compounds

  1. Prof. Dr. Armin de Meijere1 and
  2. Prof. Dr. François Diederich2
  1. Jiro Tsuji and
  2. Tadakatsu Mandai

Published Online: 30 JAN 2008

DOI: 10.1002/9783527619535.ch10

Metal-Catalyzed Cross-Coupling Reactions, Second Edition

Metal-Catalyzed Cross-Coupling Reactions, Second Edition

How to Cite

Tsuji, J. and Mandai, T. (2004) Palladium-Catalyzed Coupling Reactions of Propargyl Compounds, in Metal-Catalyzed Cross-Coupling Reactions, Second Edition (eds A. de Meijere and F. Diederich), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619535.ch10

Editor Information

  1. 1

    Institut für Organische und Biomolekulare Chemie der Georg-August-Universität, Tammannstrasse 2, D-37077 Göttingen, Germany

  2. 2

    Swiss Federal Institute of Technology Zürich, Department of Chemistry and Applied Biosciences, ETH Hönggerberg/HCI G 313, CH-8093 Zürich, Switzerland

Publication History

  1. Published Online: 30 JAN 2008
  2. Published Print: 25 AUG 2004

ISBN Information

Print ISBN: 9783527305186

Online ISBN: 9783527619535

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Keywords:

  • propargyl compounds;
  • palladium-catalyzed coupling reactions;
  • carbonylations;
  • hard carbon nucleophiles;
  • allenylpalladium intermediates

Summary

This chapter contains sections titled:

  • Introduction

  • Classification of Pd-Catalyzed Coupling Reactions of Propargyl Compounds

  • Reactions with Insertion into the sp 2 Carbon Bond of Allenylpalladium Intermediates (Type I)

  • Transformations via Transmetallation of Allenylpalladium Intermediates and Related Reactions (Type II)

  • Reactions with Attack of Soft Carbon and Oxo Nucleophiles on the sp-Carbon of Allenylpalladium Intermediates (Type III)

  • Experimental Procedures