Chapter 32. Hydrosilylation and Hydroboration of Indene — a Comparison

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. J. Dautel and
  2. S. Abele

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch32

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Dautel, J. and Abele, S. (2000) Hydrosilylation and Hydroboration of Indene — a Comparison, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch32

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Institut für Anorganische Chemie der Universität Stuttgart Pfafenwaldring 55, D-70569 Stuttgart, Germany Tel.: Int. code f (711)68.54097 —Fax: Int. code + (711)6854241

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • hydrosilylation;
  • hydroboration;
  • X-ray;
  • 29Si-NMR Spectra;
  • 11B-NMR Spectra

Summary

Hydrosilylation of indene with various hydrosilanes in the presence of Speier's catalyst leads in high yields to 1-indanyl-substituted silanes. In contrast to these results, the hydroboration of indene with HBC12SMe2 results in the 2-indanyl-substituted product. Further reactions of these derivatives are investigated. The X-ray structure determination of bis(trimethylsilylamino)2-indanylborane was carried out.