Chapter 38. Heteroaromatic-Substituted Silanes —Synthesis, Lithium Derivatives and Anionic Rearrangements

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Claudia Baum,
  2. Andrea Frenzel,
  3. Uwe Klingebiel and
  4. Peter Neugebauer

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch38

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Baum, C., Frenzel, A., Klingebiel, U. and Neugebauer, P. (2000) Heteroaromatic-Substituted Silanes —Synthesis, Lithium Derivatives and Anionic Rearrangements, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch38

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Institut für Anorganische Chemie, Georg-August-Universität Tammannstr. 4, D-37077 Göttingen, Germany Tel.: Int. code + (551)39 3052 — Fax: Int. code + (551)39 3373

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • indoylsilanes;
  • pyrroylsilanes;
  • furanylsilanes;
  • 1, 2-silyl shift;
  • macrocycle

Summary

Pure and mixed substituted indoyl-, pyrroyl-, and hranyl-silanes are formed in the reaction of heteroaromatic compounds with lithium alkyls and halosilanes (1–3). Chains of silyl-bridged molecules are available (7). The crystal structure of a lithium derivative (10) is presented and the 1, 2-silyl group migration from nitrogen to carbon is proved. Formation of a 16-membered macrocycle (12) containing four indole molecules is described.