Chapter 50. Synthesis of Silicon Synthons for a Selective Oligomer Design

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. K. Trommer,
  2. U. Herzog and
  3. G. Roewer

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch50

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Trommer, K., Herzog, U. and Roewer, G. (2000) Synthesis of Silicon Synthons for a Selective Oligomer Design, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch50

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Institut für Anorgunische Chemie Technische Universität Bergakudemie Freiberg Leipziger Str. 29, D-09596 Freiberg, Germany Tel.: Int. code + (3731)39 3174—Fax: Int. code + (3731)39 4058

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • aminosilane;
  • oligosilane

Summary

Amination of chlorosilanes with dialkylamine allows the synthesis of various chloro- and amino-substituted oligosilanes. The remaining reactive chloro sites enable to bond hrther functionalities as well as other silyl units to the silane. In this procedure the amino group is protecting potentially reactive sites at silicon atoms and can be easily exchanged by chloro substituents. By this route a desired silicon architecture can be built up.