Chapter 57. Synthesis of Linear and Cyclic Bis(trimethylsilyl)aminooligosilanes

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Waltraud Gollner,
  2. Alois Kleewein,
  3. Karin Renger and
  4. Harald Stüger

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch57

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Gollner, W., Kleewein, A., Renger, K. and Stüger, H. (2000) Synthesis of Linear and Cyclic Bis(trimethylsilyl)aminooligosilanes, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch57

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Institut für Anorganische Chemie, Technische Universität Graz Stremayrgasse 16, A-8010 Graz, Austria Tel.: Int. code + (316)873 8708 —Fax.: Int. code + (316)873 8701

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • aminochlorosilanes;
  • aminosilanes;
  • chlorosilanes

Summary

The reaction of linear (SinC12n + 2; n = 3, 4) and cyclic (Si5Cl10) chlorosilanes with one or two equivalents of lithium bis(trimethylsilyl)amide (LiN(TMS)2) results in the formation of the corresponding mono- or disubstituted aminochlorosilanes 1 -bis(trimethylsilyl)aminoheptachlorotrisilane, 1, 3-bis[bis(trimethylsilyl)amino]hexa-chlorotrisilane, 1 -bis(trimethylsilyl)aminononachlorotetrasilane, 1, 4-bis[bis(trimethyl-silyl)amino]octachlorotetrasilane, bis(trimethylsily1)aminononachlorocyclopentasilane and 1, 3-bis[bis(trimethylsilyl)amino]octachlorocyclopentasilane. The hydrogenation of the resulting products with LiAlH4 was examined.