Chapter 59. Geminal Di(hypersilyl) Compounds: Synthesis, Structure and Reactivity of Some Sterically Extremely Congested Molecules

  1. Prof. Norbert Auner3 and
  2. Prof. Johann Weis4
  1. T. Gross1,
  2. H. Oehme1 and
  3. R. Kempe2

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch59

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Gross, T., Oehme, H. and Kempe, R. (2000) Geminal Di(hypersilyl) Compounds: Synthesis, Structure and Reactivity of Some Sterically Extremely Congested Molecules, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch59

Editor Information

  1. 3

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 4

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. 1

    Fachbereich Chemie der Universität Rostock D-18051 Rostock, Germany Tel.: Int. code + (381)498 1765 —Fax: Int. code + (381)498 1763

  2. 2

    Institut für Organische Katalyseforschung an der Universität Rostock, Germany

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

SEARCH

Keywords:

  • hypersilyl compounds;
  • tris(trimethylsilyl)silyl derivates;
  • X-ray

Summary

The synthesis of derivatives of the type [(Me3Si)3Si]2CHR (R = OH, OCH3, OC(O)H, OC(O)Me, NMe2) proved to be surprisingly facile and was achieved by the reaction of tris(trimethylsilyl)silyllithium (1) with suitable C1 building blocks. The results of the X-ray analyses and reactions of these di(hypersilyl) compounds are described in this paper.