Chapter 67. Six-Membered Stannyloligosilane Ring Systems — One Ring Size, Different Combination Pattern

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Uwe Hermann,
  2. Ingo Prass,
  3. Markus Schürmann and
  4. Frank Uhlig

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch67

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Hermann, U., Prass, I., Schürmann, M. and Uhlig, F. (2000) Six-Membered Stannyloligosilane Ring Systems — One Ring Size, Different Combination Pattern, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch67

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Anorganische Chemie II, Universität Dortmund Otto-Hahn-Straße 6, D-44221 Dortmund, Germany Tel.: Int. code + (231)755 3812

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • stannylsilanes;
  • cyclic stannyloligosilanes;
  • hydridostannylsilanes

Summary

Six-membered cyclic stannyloligosilanes 1, 2 and 3 can be synthesized via the reaction of α, ω-difluoromethyloligosilanes with dichlorodiorganostannanes and magnesium. The availability of hydridostannylsilanes 11 and halogen derivatives 12, 13 and 14 allows the synthesis of ring compounds with other combination patterns such as 4, 5 and 6. X-ray structures of two stannylsilanes and a hydridostannylsilane also shown.