Chapter 73. Cyclopentadienyl (Cp)-Substituted Silanetriols and Novel Titanasiloxanes as Condensation Products

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Manuela Schneider,
  2. Beate Neumann,
  3. Hans-Georg Stammler and
  4. Peter Jutzi

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch73

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Schneider, M., Neumann, B., Stammler, H.-G. and Jutzi, P. (2000) Cyclopentadienyl (Cp)-Substituted Silanetriols and Novel Titanasiloxanes as Condensation Products, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch73

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Fakultat für Chemie, Universität Bielefeld Universitatsstr. 25, D-33615 Bielefeld Germany Tel.: Int. code + (521)106 6181 —Fax.: Int. code + (521)106 6026

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • silanetriols;
  • polyhedral titanasiloxanes;
  • hydrogen-bonded networks;
  • extended structures

Summary

A range of stable silanetriols bearing different Cp systems have been isolated. Silanetriols are useful synthons for polyhedral metallasiloxanes. Condensation of Cp silanetriols with titanium alkoxides yielded oligomeric titanasiloxanes with interesting structural features. Transformation of such polyhedra into extended structures by CpSi bond splitting has been pursued. Furthermore these compounds can be considered as valuable model systems for titanasilicates.