Chapter 80. Zwitterionic spirocyclic λ5si-Silicates Containing Diolato(2–) Ligands Derived from Acetohydroximic Acid and Benzohydroximic Acid

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Andreas Biller,
  2. Brigitte Pfrommer,
  3. Melanie Pülm and
  4. Reinhold Tacke

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch80

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Biller, A., Pfrommer, B., Pülm, M. and Tacke, R. (2000) Zwitterionic spirocyclic λ5si-Silicates Containing Diolato(2–) Ligands Derived from Acetohydroximic Acid and Benzohydroximic Acid, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch80

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Institutfür Anorganische Chemie, Universität Würzburg Am Hubland, D-97074 Würzburg, Germany Tel.: Int. code + (931)8885250 —Fax: Int. code + (931)8884609

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • pentacoordinate silicon;
  • zwitterionic λ5Si-silicates;
  • crystal structures;
  • acetohydroximato(2-) ligand;
  • benzohydroximato(2-) ligand

Summary

Derivatives of a new class of zwitterionic spirocyclic λ'S-silicates with an SiO4 framework have been prepared. The syntheses and the properties of these molecular pentacoordinate silicon compounds are reported. The crystal structures of two of the zwitterions are described.