Chapter 9. The Quest for Silaketene

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Günther Maier and
  2. Hans Peter Reisenauer

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch9

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Maier, G. and Reisenauer, H. P. (2000) The Quest for Silaketene, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch9

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Heiko Egenorf Institut für Organische Chemie Justus-Liebig- Universität Gießen Heinrich-Buff-Ring 58, D-35392 Gießen, Germany Fax: Int. Code + (641)9934309

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • matrix isolation;
  • photoisomerizations;
  • cocondensation

Summary

Evaporation of silicon atoms and consecutive cocondensation with formaldehyde in an argon matrix was used to generate two CH2OSi isomers, namely silaoxiranylidene and silaketene. The latter can be considered as a complex of carbon monoxide and silylene rather than as a true (planar) ketene. Structural assignments for the observed species are carried out by comparison of experimental and calculated IR spectra and thus are a good example for the combination of quantum chemical calculations and experimental work. Theoretical aspects of the CH2OSi energy hypersurface as well as the photochemistry of the observed silaketene are compared with earlier results.