Chapter 96. Synthesis, Functionalization and Cross-Linking Reactions of Poly(silylenemethylene)s

  1. Prof. Norbert Auner2 and
  2. Prof. Johann Weis3
  1. Wolfram Uhlig

Published Online: 28 APR 2008

DOI: 10.1002/9783527619917.ch96

Organosilicon Chemistry IV: From Molecules to Materials

Organosilicon Chemistry IV: From Molecules to Materials

How to Cite

Uhlig, W. (2000) Synthesis, Functionalization and Cross-Linking Reactions of Poly(silylenemethylene)s, in Organosilicon Chemistry IV: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619917.ch96

Editor Information

  1. 2

    Inst. für Anorganische Chemie, der Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany, Phone: 0 69/7 98-29180, -29591, Fax: 069/798-29188

  2. 3

    Wacker-Chemie GmbH, Geschäftsbereich S, Werk Burghausen, Johannes-Hess-Strasse 24, D-84489 Burghausen, Germany

Author Information

  1. Laboratorium für Anorganische Chemie Eidgenössische Technische Hochschule Zürich ETH-Zentrum, CH-8092 Zürich, Switzerland Tel.: Int. code + 16322858 — Fax: Int. code + 16321149

Publication History

  1. Published Online: 28 APR 2008
  2. Published Print: 17 JAN 2000

ISBN Information

Print ISBN: 9783527298549

Online ISBN: 9783527619917

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Keywords:

  • organosilicon polymer;
  • poly(silylenemethylene);
  • silyl triflate

Summary

Novel poly(silylenemethylene)s have been prepared by ring-opening polymerization of 1,3–disilacyclobutanes followed by a protodesilylation reaction with triflic acid. Reactions of the triflate derivatives with organomagnesium compounds, LiAlH4, amines or alcohols gave functional substituted and branched poly(silylene-methylene)s, which may serve as suitable precursors for silicon carbide and Si/C/N-based materials.