Chapter 102. Polycarbosilanes as Precursors of Novel Membrane Materials

  1. Prof. Dr. Norbert Auner2 and
  2. Prof. Dr. Johann Weis3
  1. Hieronim Maciejewski,
  2. Piotr Pawluć,
  3. Bogdan Marciniec,
  4. Ireneusz Kownacki,
  5. Wioletta Maciejewska and
  6. Mariusz Majchrzak

Published Online: 5 MAY 2008

DOI: 10.1002/9783527619924.ch102

Organosilicon Chemistry V: From Molecules to Materials

Organosilicon Chemistry V: From Molecules to Materials

How to Cite

Maciejewski, H., Pawluć, P., Marciniec, B., Kownacki, I., Maciejewska, W. and Majchrzak, M. (2003) Polycarbosilanes as Precursors of Novel Membrane Materials, in Organosilicon Chemistry V: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619924.ch102

Editor Information

  1. 2

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 3

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Author Information

  1. Adam Mickiewicz University, Faculty of Chemistry Grunwaldzka 6, 60-780 Poznań, Poland Tel.: +48 618291366 — Fax: +48 618291508

Publication History

  1. Published Online: 5 MAY 2008
  2. Published Print: 26 SEP 2003

ISBN Information

Print ISBN: 9783527306701

Online ISBN: 9783527619924

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Keywords:

  • hydrosilylation;
  • polycarbosilane;
  • karstedt catalyst;
  • membrane materials

Summary

Polycarbosilanes and crosslinked polycarbosilanes were obtained by using a polyhydrosilylation reaction between difuncional vinylsilanes and difunctional hydrosilanes or in the intermolecular hydrosilylation of monomers containing an Si-H bond and an SiCH[DOUBLE BOND]CH2 group in the same molecule. Poly(silylene-ethylenearylene)s were obtained with the highest molecular weight. They seem to be potential parent substances for future applications as a membrane materials.